Preparation and structures of hydrido(organosilyl)arenethiolatorhodium(III) complexes with PMe3 ligands. Irreversible and reversible oxidative addition of an Si-H bond to thiolatorhodium(I) complexes

DOI: 10.1016/s0020-1693(97)05449-2

Source and publish data:

Inorganica Chimica Acta p. 203 - 211 (1997)

Update date:2022-08-04

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Authors:

Osakada, Kohtaro

Hataya, Kouji

Yamamoto, Takakazu

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Article abstract of DOI:10.1016/s0020-1693(97)05449-2

Thiolatorhodium(I) complexes, Rh(SAr)L₃ (Ar = Ph (1), C₆H₄-p-Me (2), C₆H₄-p-OMe (3); L = PMe₃), react with HSi(OMe)₃ and with HSiCl₃ to give hydrido(silyl)arenethiolat

Full text of DOI:10.1016/s0020-1693(97)05449-2

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Product name:RhH(SiH(C₆H₄-p-F)2)(SC₆H₄-p-Me)(PMe₃)3

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