Chemical and Pharmaceutical Bulletin p. 971 - 980 (1997)
Update date:2022-08-05
Topics:
Tsuda, Yoshisuke
Noguchi, Shinsuke
Kanemitsu, Kimihiro
Sato, Yoshiyuki
Kakimoto, Kyoko
Iwakura, Yumiko
Hosoi, Shinzo
Pyranoside 3,4-cis-thionocarbonates, under radical-promoted reaction conditions (method A, B, or C, described in the text), gave O-S rearrangement products, 3,4-thiolcarbonates of cis-stereochemistry, in acceptable yields. 2,3-Thionocarbonates of trans-stereochemistry also gave the rearrangement products of cis-stereochemistry preferentially in method B (photolysis with hexabutyldistannane). Although regio-control of the product was not satisfactory in most cases, some of the results suggested that the regioselectivity of the reaction is markedly influenced by the stereochemistry of the anomeric position of the substrates. The products were converted to thioglycosides (peracetate forms) by conventional means.
View MoreShanghai SMEC Trading Co., Ltd.
website:http://www.shanghaismec.com
Contact:+86-21-68811293
Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Shandong Zhongcheng Barium Salt Co., Ltd
Contact:+86-15725732638
Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Zhejiang Kangfeng Chemical Co.,LTD.
Contact:+86-579-86709687
Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Zhejiang Genebest Pharmaceutical Co.,Ltd.
Contact:0086-571-63532866
Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Contact:13357117572
Address:No.149 Shiji dadao Road.
Doi:10.1055/s-2007-966055
(2007)Doi:10.1016/s0020-1693(97)05446-7
(1997)Doi:10.1021/jo01258a038
(1969)Doi:10.1021/jo982242b
(1999)Doi:10.1016/S0022-328X(97)00135-6
(1997)Doi:10.1016/S0040-4039(01)95837-X
(1973)
