Tetrahedron Letters p. 5917 - 5920 (1997)
Update date:2022-08-04
Topics:
Coleman, Robert S.
Sarko, Christopher R.
Gittinger, Jens P.
Three concise enantioselective synthetic routes to the C17-C21 epoxyacid segment of the azinomycins are presented and were based on a Sharpless asymmetric epoxidation/kinetic resolution of racemic allylic alcohol (±)-3 that occurred with reversal of the expected sense of enantioselection.
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Doi:10.1021/jm00143a009
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