Reactions of 1-aryl-2-bromodiazene 1-oxides with acids and bases

DOI: 10.1007/BF02495423

Source and publish data:

Russian Chemical Bulletin p. 592 - 594 (1997)

Update date:2022-08-03

Topics:

Authors:

Tyurin Tyurin

Churakov

Ioffe Ioffe

Strelenko

Tartakovsky

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Article abstract of DOI:10.1007/BF02495423

The reactions of 1-aryl-2-bromodiazene 1-oxides with HCl in nonaqueous media give aryldiazonium chlorides, while 1,3,3-substituted triazenes-1 are formed in the reactions with secondary amines. Using 2-(¹⁵N) label, it was shown that the aryl group does not migrate in these reactions.

Full text of DOI:10.1007/BF02495423

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