Macrocycle opening in crown ethers 3. * Transformation of 4′-nitrobenzocrown ethers into podands in the reaction with methylamine

DOI: 10.1007/BF02495407

Source and publish data:

Russian Chemical Bulletin p. 519 - 522 (1997)

Update date:2022-08-05

Topics: Starting Material

Authors:

Gromov Gromov

Dmitrieva

Krasnovsky

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Article abstract of DOI:10.1007/BF02495407

A method for the synthesis of nitrogen-containing podands from 4′-nitrobenzocrown ethers was developed. It involves nucleophilic regioselective cleavage of the macrocycle upon heating with MeNH₂.

Full text of DOI:10.1007/BF02495407

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