Reductive diallylation of natural amino acids with triallylborane. The first synthesis of chiral 1,1-diallyl-2-amino alcohols and their cyclization into optically active pyrrolidines

DOI: 10.1016/S0040-4039(97)01402-0

Source and publish data:

Tetrahedron Letters p. 6259 - 6262 (1997)

Update date:2022-08-03

Topics:

Authors:

Bubnov, Yuri N.

Misharin, Mikhail A.

Ignatenko, Anatoly V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)01402-0

The titled amino alcohols are obtained by treatment of chiral amino acids with triallylborane. Electrophylic iodocyclization of the alcohols leads to pyrrolidine derivatives.

Full text of DOI:10.1016/S0040-4039(97)01402-0

Products guided by the article

Product name:L-2-(diallylhydroxymethyl)pyrrolidine

Cas No:195391-98-1

R&D Labs maybe for 195391-98-1

Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Dragon Chemical Co., Ltd.

Contact:0571-

Address:zhejing
xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China
Jiangsu Seed Chem Co.,Ltd.

Contact:86-513-84128750/13773795976

Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui

Relevant to this article

Efficient asymmetric synthesis of phosphatidyl-D-myo-inositol 3,4,5- trisphosphate

Doi:10.1248/cpb.45.1521
(1997)
Synthesis, biological evaluation and molecular docking study of 2-substituted-4, 6-diarylpyrimidines as α-glucosidase inhibitors

Doi:10.3390/molecules22111865
(2017)
Azamorphinan and related compounds. I. A synthesis of 2-hydroxy-N-methyl-9-azamorphinan (studies on the syntheses of heterocyclic compounds. CCXIV.

Doi:10.1248/cpb.16.296
(1968)
Multiply bridged organodiantimony(V) compounds; crystal structures of [(SbR₂)₂(μ-O)₂(μ-O₂AsMe ₂)₂] (R = Ph or p-tolyl) and [(SbR₃)₂(μ-O)(μ-O₂MR′ ₂)₂] (R = Ph, M = P, R′ = Me; R = Ph, M = As, R′ = Me or Ph; R = p-tolyl, M = P, R′ = Me)

Doi:10.1039/a702244a
(1997)
Preparation and Use of Aziridino Alcohols as Promoters for the Enantioselective Addition of Dialkylzinc Reagents to N-(Diphenylphosphinoyl) Imines

Doi:10.1021/jo970918h
(1997)
Synthesis and absolute configuration of two defensive alkaloids from the Mexican bean beetle, Epilachna varivestis

Doi:10.1016/S0040-4039(97)01491-3
(1997)

Article Doi