
Synlett p. 899 - 902 (1997)
Update date:2022-08-03
Topics:
Yasuda, Minoru
Ide, Mitsuaki
Matsumoto, Yuka
Nakata, Masaya
The enantiospecific synthesis of the 14-membered diene unit of methyl sarcophytoate has been achieved by using the Sharpless asymmetric epoxidation, the aldol reaction, the oxy-Michael addition, and the modified Ito-Kodama cyclization as the key steps. All the carbon skeleton was derived from geraniol only.
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Doi:10.1246/bcsj.56.1791
(1983)Doi:10.1007/BF01031774
()Doi:10.1016/S0040-4020(97)00544-9
(1997)Doi:10.1021/jo970445e
(1997)Doi:10.1039/a602018f
(1997)Doi:10.1007/BF00474868
()