Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate

DOI: 10.1055/s-1997-967

Source and publish data:

Synlett p. 899 - 902 (1997)

Update date:2022-08-03

Topics:

Authors:

Yasuda, Minoru

Ide, Mitsuaki

Matsumoto, Yuka

Nakata, Masaya

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Article abstract of DOI:10.1055/s-1997-967

The enantiospecific synthesis of the 14-membered diene unit of methyl sarcophytoate has been achieved by using the Sharpless asymmetric epoxidation, the aldol reaction, the oxy-Michael addition, and the modified Ito-Kodama cyclization as the key steps. All the carbon skeleton was derived from geraniol only.

Full text of DOI:10.1055/s-1997-967

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