Bulletin of the Chemical Society of Japan p. 1791 - 1794 (1983)
Update date:2022-08-03
Topics:
Satoh
Suginome
Tokuda
Electrolysis of allyl chloride and five molar excess of acetone in hexamethylphosphoric triamide containing 0. 5 M tetrabutylammonium perchlorate gave an addition product, 2-methyl-4-penten-2-ol, in a 53% yield. Allyl groups of 1-chloro-2-methyl-2-propene, 1-chloro-2-butene(3), 3-chloro-1-butene(4), 1-chloro-3-methyl-2-butene(5), and 3-chloro-3-methyl-1-butene(6), and benzyl groups of benzyl chloride, benzyl bromide, and 1-chloro-1-phenylethane can similarly be added to acetone by electrolysis to give the corresponding alcohols in fair to good yields. Among these electrochemical reactions, those of 3, 4, 5 and 6 with acetone give respectively two isomeric homoallyl alcohols, one of the isomers is not accessible by the usual chemical reaction between allylic organometallics and acetone.
View MoreContact:86 513 85512619
Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
Contact:0792-8228321
Address:10TH Floor No.121 binjiang Road Xunyang District
Changzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
Xiamen Goodhealth Pharmchem Co., Ltd.
Contact:0086-592-2097683
Address:404R No.2 54# Minzu Rd., Xiamen, China
website:http://www.sagechem.com
Contact:+86-571-86818502
Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Doi:10.1016/S0040-4020(97)00714-X
(1997)Doi:10.1016/S0040-4039(97)01638-9
(1997)Doi:10.1016/S0957-4166(98)00149-9
(1998)Doi:10.1021/ja01016a042
(1968)Doi:10.1021/jo060089c
(2006)Doi:10.1021/jm000957c
(2000)