Chemistry Letters p. 855 - 856 (1997)
Update date:2022-08-03
Topics:
Tsuji, Kyoko
Fujii, Yuuichi
Sasaki, Shigeru
Yoshifuji, Masaaki
Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.
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