Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

DOI: 10.1246/cl.1997.845

Source and publish data:

Chemistry Letters p. 845 - 846 (1997)

Update date:2022-08-03

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Authors:

Oishi, Tohru

Shoji, Mitsuru

Kumahara, Naomi

Hirama, Masahiro

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Article abstract of DOI:10.1246/cl.1997.845

Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (R)-(E)-1-benzyloxy-2-hydroxy-3-pentene via Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.

Full text of DOI:10.1246/cl.1997.845

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