Tetrahedron Letters p. 5847 - 5850 (1997)
Update date:2022-08-02
Topics:
Solladie, Guy
Hanquet, Gilles
Rolland, Catherine
A new route to enantiopure syn and anti 1,2-diols is described from oxalyl-di-(N-methyl-N-methoxyamide) via the corresponding β-ketosulfoxide. This is the first report of the stereoselective reduction of a γ-keto-β-hydroxysulfoxide.
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