Chemical Communications p. 1759 - 1760 (1997)
Update date:2022-07-30
Topics:
Back, Thomas G.
Minksztym, Kazimierz
The free-radical addition of phenyl trichloromethyl selenide to alkenes affords 2-phenylseleno-1-trichloromethylalkanes, which can be converted into α,β-unsaturated carboxylic acids or amides by base-promoted dehydrochlorination, followed by [2,3]sigmatropic rearrangement of the corresponding selenoxides in the presence of water or diethylamine, respectively.
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