Tetrahedron Letters p. 5195 - 5198 (1998)
Update date:2022-08-03
Topics:
Masui, Moriyasu
Shioiri, Takayuki
Asymmetric reduction of α-oxoketoxime ethers with the reagents prepared in situ from trimethyl borate and chiral amino alcohols derived from either L-proline or α-pinene was investigated. Both cyclic and acyclic α- oxoketoxime ethers were reduced to afford the corresponding chiral 1,2amino alcohols with high enantioselectivities.
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