Journal of Organic Chemistry p. 1978 - 1986 (2004)
Update date:2022-08-05
Topics:
Fernandez De La Pradilla, Roberto
Buergo, Maria Victoria
Martinez, Maria Victoria
Montero, Carlos
Tortosa, Mariola
Viso, Alma
The treatment of sulfinyl chlorohydrins with KO-t-Bu in THF generates epoxy vinyl sulfoxides that undergo an efficient base-induced rearrangement to generate enantiopure hydroxy 2-sulfinyl dienes. This novel process takes place with high chemo- and stereo
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