Tetrahedron Letters p. 615 - 618 (1986)
Update date:2022-08-03
Topics:
Endo, Takeshi
Takada, Tadayoshi
Okawara, Makoto
The reduction of rhodizonic acid (RA) with 1-benzyl-1,4-dihydronicotinamide (BNAH; NADH model) was carried out at room temperature to obtain tetrahydroxy-p-quinone (THQ) and hexahydroxybenzene (HHB) by two-electron and four-electron reductions, respectively.The reduction of methyl benzoylformate with BNAH proceded smoothly in the presence of RA, although it could not be reduced at all without RA.
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