[Ru(η5-C5Me5)(Me2NCH 2CH2NMe2)]+, a stable 16-eleetron complex. Reaction with dioxygen and formation of a monomeric hydroxoruthenium tetramethylfulvene complex

DOI: 10.1021/om9706774

Source and publish data:

Organometallics p. 5601 - 5603 (1997)

Update date:2022-09-26

Topics:

Authors:

Gemel, Christian

Mereiter, Kurt

Schmid, Roland

Kirchner, Karl

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om9706774

NaBAr′₄ (Ar′ = 3,5-C₆H₃(CF₃)₂) abstracts chloride from Ru(η⁵-C₅Me₅)(Me₂NCH ₂CH₂NMe₂)Cl (1) in Et₂O to give the stable cationic 16e complex [Ru(η⁵-C₅Me₅)(Me₂NCH ₂CH₂NMe₂)]BAr′₄ (2). Exposure of a Et₂O solution of 2 to air at room temperature yields the novel monomeric hydroxotetramethylfulvene complex [Ru(η⁶-C₅Me₄CH₂)(Me ₂NCH₂CH₂NMe₂)(OH)]BAr′ ₄ (4).

Full text of DOI:10.1021/om9706774

Products guided by the article

Product name:[Ru(η(5)-C5Me5)(Me2NCH2CH2NMe2)(O2)][B(3,5-C6H3(CF3)2)4]

Cas No:199274-58-3

R&D Labs maybe for 199274-58-3

Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
SHIJIAZHUANG AGERUO-BIOTECH CO.LTD

Contact:+86-130-2866-6699

Address:Huaian east Road 158
Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
CGeneTech (Suzhou, China) Co., Ltd.

Contact:+86-512-62956962

Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park

Relevant to this article

Reactivity of mixed-metal BaCu and BaY β-diketonatoalkoxides with Lewis bases.

Doi:10.1016/0277-5387(95)00295-4
(1996)
Trifluoromethanesulfonic Anhydride-4-(N,N-Dimethylamino)pyridine as a Reagent Combination for Effecting Bischler-Napieralski Cyclisation under Mild Conditions: Application to Total Syntheses of the Amaryllidaceae Alkaloids N-Methylcrinasiadine, Anhydrolyc

Doi:10.1039/c39950002551
(1995)
Structure-guided design of a methyl donor cofactor that controls a viral histone H3 lysine 27 methyltransferase activity

Doi:10.1021/jm201000j
(2011)
Syntheses, Raman and Infrared Vibrational Spectra, Normal Coordinate Analyses and 29Si-NMR-Spectra of Halogenated Trisilanes Me_nSi3X_8-n and (H_mX_3-mSi)2SiMe2 (X=F, Cl, Br, I)

Doi:10.1016/0022-2860(95)08734-D
(1995)
Chemical aspects of the benzophenone-photosensitized formation of two lysine - 2′-deoxyguanosine cross-links

Doi:10.1021/ja00155a005
(1995)
Synthesis of highly enantiomerically enriched N-Boc-α-amino ketones from pseudoephedrine N-Boc-α-amino acid amides

Doi:10.1016/0040-4039(95)02053-5
(1995)

Article Doi