Arm-off reactions of the tripodal polyphosphane MeC(CH2PPh2)3 in octahedral rhodium(III) complexes of heterocyclic thioamides

DOI: 10.1016/S0020-1693(97)05549-7

Source and publish data:

Inorganica Chimica Acta p. 39 - 48 (1998)

Update date:2022-08-04

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Authors:

Brandt, Katja

Sheldrick, William S.

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Article abstract of DOI:10.1016/S0020-1693(97)05549-7

Arm-off κ³P → κ²P processes of the tripodal polyphosphane MeC(CH₂PPh₂), have been studied for reactions of [RhCl₃(triphos)] (1a) and [Rh(MeCN)₃(triphos)](CF₃SO₃)₃

Full text of DOI:10.1016/S0020-1693(97)05549-7

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Product name:Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)]CF₃SO₃

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