Synthesis p. 1261 - 1267 (1997)
Update date:2022-08-04
Topics:
Gerster
Renaud
The stereochemical outcome of reactions mediated by tertiary 1,3-dioxolan-4-yl and oxiranyl cyclic radicals has been investigated. The presence of a very bulky substituent next to the radical center has a remarkable syn directing effect. These stereoselectivities are rationalized by a model which takes into account radical pyramidalization, steric interactions between the substituents attached to the cycle and steric interactions with the incoming radical trap.
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Doi:10.1246/cl.1997.1191
(1997)Doi:10.1021/jo971148c
(1998)Doi:10.1016/j.dyepig.2013.06.010
(2013)Doi:10.1016/s0022-328x(97)00369-0
(1997)Doi:10.1002/ejoc.200500096
(2005)Doi:10.1016/S0022-328X(97)00387-2
(1997)
