Synthesis p. 366 - 371 (1986)
Update date:2022-08-04
Topics:
Hopkinson, A. C.
Lee-Ruff, E.
Maleki, M.
Rearrangement of α-alkoxycarbonyldiarylmethyl cations lead to 9-fluorenecarboxylic esters.Decarboxylation of these esters generates the fluorene derivatives 9a-f.The precursors to the cations are the α-hydroxyesters 6a-g.This conversion constitutes a facile synthesis of benzofluorenes.
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