Stereocontrolled access to carba-C-disaccharides via functionalized dienylsilanes

DOI: 10.1016/S0040-4039(97)10389-6

Source and publish data:

Tetrahedron Letters p. 8845 - 8848 (1997)

Update date:2022-08-04

Topics:

Authors:

Angelaud, Remy

Landais, Yannick

Parra-Rapado, Liliana

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Article abstract of DOI:10.1016/S0040-4039(97)10389-6

We report here the total synthesis of a class of C1 → C6 Carba-C-disaccharide, formed by the association between a 2-deoxyglucose as the sugar unit and a pseudo-pyranose or a pseudo-furanose as the carba-sugar moiety. The carba-sugar fragments were assembled from the corresponding dienylsilanes through a dihydroxylation-cyclopropanation sequence.

Full text of DOI:10.1016/S0040-4039(97)10389-6

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