Synthesis and spectroscopic investigations of Mn(II), Co(II), Ni(II), Rh(III), Ru(III) and Ir(III) complexes with 2-furyl (m-aminophenylenimine)methyl ketone

Article abstract of DOI:10.1080/00945719708003160

A new tridentate ligand, 2-furyl (m-aminophenylenimine)methyl ketone (FAMK), was synthesised from m-phenylenediamine and furanglyoxal. Its metal complexes of the general formula [M(FAMK)X₂H₂O], where M = Mn(II), Co(II) and Ni(II) and [M(FAMK)X₃], where M = Rh(III), Ru(III) and Ir(III) have been prepared. On the basis of chemical analyses, magnetic moment measurements, IR and electronic spectra, an octahedral geometry of the ligand around the metallic ions has been suggested. The fungicidal activities of the ligand and its metal complexes have also been studied.

Full text of DOI:10.1080/00945719708003160

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis and Spectroscopic
Investigations of Mn(II), Co(II),
Ni(II), Rh(III), Ru(III) and Ir(III)
Complexes with 2-Furyl (m-
Aminophenylenimine)methyl
Ketone
Sanjay Vats a & L. M. Sharma a
a Department of Chemistry , Nanak Chand Anglo
Sanskrit (Post Graduate) College Chaudhary Charan
Singh University , Meerut, 250 001, India
Published online: 22 Aug 2006.
To cite this article: Sanjay Vats & L. M. Sharma (1997) Synthesis and Spectroscopic
Investigations of Mn(II), Co(II), Ni(II), Rh(III), Ru(III) and Ir(III) Complexes with 2-Furyl
(m-Aminophenylenimine)methyl Ketone, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 27:10, 1565-1579, DOI: 10.1080/00945719708003160
To link to this article: http://dx.doi.org/10.1080/00945719708003160
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