Scholarly article on Cr(CO)3(C6H4CH2C5H(CH3)2NC6H5)(1+)*PF6(1-)=[Cr(CO)3(C6H4CH2C5H(CH3)2NC6H5)]PF6 201486-04-6 from Journal of Organometallic Chemistry p. 357 - 368

DOI: 10.1016/s0022-328x(97)00369-0

Source and publish data:

Journal of Organometallic Chemistry p. 357 - 368 (1997)

Update date:2022-08-04

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Authors:

Robin-Le Guen

Senechal-Tocquer

Senechal

Caro Caro

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Article abstract of DOI:10.1016/s0022-328x(97)00369-0

Diacetylation of benehrotrenic alkenes by acetic anhydride and weak Lewis acid (ZnCl₂, BF₃-OEt₂) is reported. A series of γ-benchrotrenic pyrylium salts is obtained together with the mono and the diacetylated products. The first organometallic fused rings pyrylium salts are obtained. In connection with the electron donating effect of the Cr (CO)₃ group, the influence of rings deconjugation on NMR data is discussed. Finally the reaction of acyclic and cyclic γ-benchrotrenic pyrylium salts with nucleophiles is described.

Full text of DOI:10.1016/s0022-328x(97)00369-0

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Product name:Cr(CO)3(C₆H₄CH₂C₅H(CH₃)2NC₆H₅)⁽¹⁺⁾*PF₆^(1-)=[Cr(CO)3(C₆H₄CH₂C₅H(CH₃)2NC₆H₅)]PF₆

Cas No:201486-04-6

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DOI: 10.1016/s0022-328x(97)00369-0