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Preparation of useful synthetic intermediates of taxol analogs, cyclooctenone derivatives

DOI: 10.1248/cpb.45.2113

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2113 - 2115 (1997)

Update date:2022-08-04

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Authors:

Yamada, KojiYamada, Koji

Tozawa, TakashiTozawa, Takashi

Saitoh, KatsuyukiSaitoh, Katsuyuki

Mukaiyama, TeruakiMukaiyama, Teruaki

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Article abstract of DOI:10.1248/cpb.45.2113

Stereoselective syntheses of ω-(α-bromoketo) octanals and nonanal with oxygenated functions and formation of the corresponding eight-membered carbocyclic aldols by subsequent samarium(II)-mediated cyclization are demonstrated. Cyclooctenones deoxygenated

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Full text of DOI:10.1248/cpb.45.2113

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