New macrocyclic oligoboronates

DOI: 10.1016/S0022-328X(97)00183-6

Source and publish data:

Journal of Organometallic Chemistry p. 71 - 78 (1997)

Update date:2022-08-05

Topics:

Authors:

Hoepfl, Herbert

Farfan, Norberto

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Article abstract of DOI:10.1016/S0022-328X(97)00183-6

Two new macrocyclic oligoboronates were prepared in easy one step synthesis from aminodialcohols and phenylboronic acid.Reaction of 2,6-pyridinemethanol gives a tetrameric species, while 2-(salicylideneamino)-1-hydroxyethane provides a cyclobisboronate.Both compounds are characterized by using X-ray structural analyses.Possible applications in the supramolecular host-guest chemistry are discussed. - Keywords: macrocyclic boron complexes; self-assembly; host-guest

Full text of DOI:10.1016/S0022-328X(97)00183-6

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Product name:4,14,24,34-tetraphenyl-[3,5,13,15,23,25,33,35]octaoxa[41,42,43,44]tetraaza[4,14,24,34]-tetraborapentacyclo[31.3.1.1(7,11).1(27,31)]dotriaconta-1⁽⁴¹⁾,7,9,11⁽⁴²⁾,17,19,21⁽⁴³⁾,27,29,31⁽⁴⁴⁾,37,39-dodecaene

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