Regiocontrol of Diels-Alder reaction of conjugate 1-trienol ether in chiral tropilidene with TCNE

DOI: 10.1246/cl.1999.179

Source and publish data:

Chemistry Letters p. 179 - 180 (1999)

Update date:2022-08-02

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Authors:

Sugimura, Takashi

Nagano, Shinya

Kohno, Harumi

Fujita, Morifumi

Tai, Akira

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Article abstract of DOI:10.1246/cl.1999.179

The Diels-Alder reaction of tetracyanoethylene (TCNE) with a 1-trienol unit in the tropilidenes at the 1,4-position was a quick and reversible process, whereas the 3,6-addition only proceeded in polar solvent and was irreversible.

Full text of DOI:10.1246/cl.1999.179

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