Conversion of meso-alkenes to chiral alkenes via titanocene-catalyzed ring-opening/ring-closing olefin metathesis

DOI: 10.1016/S0022-328X(97)00203-9

Source and publish data:

Journal of Organometallic Chemistry p. 41 - 48 (1997)

Update date:2022-07-30

Topics:

Authors:

Halterman, Ronald L.

Ramsey, Timothy M.

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Article abstract of DOI:10.1016/S0022-328X(97)00203-9

The preparation of 7-anti-(3-methyl-3-butenyl)norbornene 11 is described. This meso-symmetrical diene underwent ring-opening/ring-closing olefin metathesis catalyzed by bis(cyclopentadienyl)titanacyclobutane 4 to give (1R*,6R* 7S* )-7-ethenyl-3-methylbicy

Full text of DOI:10.1016/S0022-328X(97)00203-9

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