Tetrahedron p. 1221 - 1232 (1998)
Update date:2022-07-29
Topics:
Cancho, Yolanda
Martin, Joan M.
Martinez, Maria
Llebaria, Amadeu
Moreto, Josep M.
Delgado, Antonio
The nickel promoted tandem cyclization-quenching of tethered aminobromodienes has been extended to the synthesis of 2,3,4-trisubstituted pyrrolidines. By a judicious choice of substituents on the starting aminohalodiene, the diastereoselectivity of the process can be efficiently controlled. When a chiral auxiliary on the nitrogen atom is used, enantiomerically enriched pyrrolidines can be obtained after removal of the auxiliary.
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Doi:10.1021/jo970813e
(1998)Doi:10.1016/S0040-4020(97)10362-3
(1998)Doi:10.1080/00397919808005079
(1998)Doi:10.1002/cmdc.202000183
(2020)Doi:10.1021/jm9707378
(1998)Doi:10.1021/cb4005832
(2013)
