Bulletin of the Chemical Society of Japan p. 475 - 482 (1998)
Update date:2022-08-05
Topics:
Koga, Yuji
Kusama, Hiroyuki
Narasaka, Koichi
By the catalytic use of a rhenium(I) nitrogen complex, [ReCl(N2)(PMe2Ph)4], α-keto radicals are generated from α-bromo ketones and react with vinyl ethers and silyl enol ethers intermolecularly. Various substituted furans, including tetrasubstituted furans such as furoguaiacin, are prepared by this method.
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