A detailed investigation of the preparation of 2,7-diaminosuberic acid and 2,5-diaminoadipic acid derivatives using Kolbe electrolysis

DOI: 10.1016/S0040-4020(97)10412-4

Source and publish data:

Tetrahedron p. 2059 - 2074 (1998)

Update date:2022-08-05

Topics:

Authors:

Hiebl, Johann

Blanka, Michael

Guttman, Andras

Kollmann, Hermann

Leitner, Kornelia

Mayrhofer, Guenter

Rovenszky, Franz

Winkler, Karin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(97)10412-4

The yield of protected 2,7-diaminosuberic acid (DAS) prepared by Kolbe reaction of N-protected α-glutamic acid esters is dependent on solvent, temperature, concentration of carboxylate onion, and protecting groups. The highest yield of protected L,L-2,7-diaminosuberic acid is obtained with Boc-Glu-OMe as starting material using MeOH/pyridine/NaOMe as electrolyte.

Full text of DOI:10.1016/S0040-4020(97)10412-4

Products guided by the article

Product name:(S)-2-tert-Butoxycarbonylamino-pentanedioic acid 5-benzyl ester 1-[2-(toluene-4-sulfonyl)-ethyl] ester

Cas No:203940-79-8

R&D Labs maybe for 203940-79-8

Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.

Contact:+86-15853188990

Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
U-Chemo Holding Co.,Limited

website:http://www.u-chemo.com

Contact:+86-21-61558312

Address:Dong Fang Road,
Jinan Great Chemical Co.,Ltd.

Contact:+86-531-58668191 58668193 58668196 58661173

Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.

Relevant to this article

Indium-mediated highly diastereoselective allenylation in aqueous medium: Total synthesis of (+)-goniofufurone

Doi:10.1039/a707881a
(1998)
Synthesis of piericidin analogues, inhibitors on electron transport system in mitochondria

Doi:10.1271/bbb1961.44.2913
(1980)
Synthesis and evaluation of a new chiral ligand: 2-diphynlarsino-2'- diphenylphosphino-1,1'-binaphthyl (BINAPAs)

Doi:10.1016/S0040-4039(98)00041-0
(1998)
Synthesis and antitumor activity of duocarmycin derivatives: Modification at the C-7 position of segment-A of A-ring pyrrole compounds

Doi:10.1016/S0968-0896(00)00046-8
(2000)
Generation and Cycloadditions of 2-(N-acylamino)-1-thia-1,3-dienes part III: Control of diastereoselectivity using homochiral auxiliaries

Doi:10.1016/S0040-4020(98)00067-2
(1998)
Synthesis, structure and reactivity of a new six-membered cycloaurated complex of 2-benzoylpyridine [AuCl₂(pcp-C¹,N)] [pcp = 2-(2-pyridylcarbonyl)phenyl]. Comparison with the cycloaurated complex derived from 2-benzylpyridine

Doi:10.1039/a706354g
(1998)

Article Doi