Generation and Cycloadditions of 2-(N-acylamino)-1-thia-1,3-dienes part III: Control of diastereoselectivity using homochiral auxiliaries

DOI: 10.1016/S0040-4020(98)00067-2

Source and publish data:

Tetrahedron p. 3219 - 3234 (1998)

Update date:2022-08-05

Topics: Diastereoselectivity Cycloadditions Generation

Authors:

Bell, Andrew S.

Fishwick, Colin W. G.

Reed, Jessica E.

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Article abstract of DOI:10.1016/S0040-4020(98)00067-2

Activated 2-(N-acylamino)-1-thia-1,3-dienes undergo efficient diastereoselective Diels-Alder cycloadditions giving access to thiopyrans of high optical purity. By variation of the position and nature of the chiral auxiliaries we have been able to induce a

Full text of DOI:10.1016/S0040-4020(98)00067-2

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