Tetrahedron p. 3219 - 3234 (1998)
Update date:2022-08-05
Topics: Diastereoselectivity Cycloadditions Generation 2-(N-acylamino)-1-thia-1,3-dienes Homochiral auxiliaries
Bell, Andrew S.
Fishwick, Colin W. G.
Reed, Jessica E.
Activated 2-(N-acylamino)-1-thia-1,3-dienes undergo efficient diastereoselective Diels-Alder cycloadditions giving access to thiopyrans of high optical purity. By variation of the position and nature of the chiral auxiliaries we have been able to induce a
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