Tetrahedron (2020)
Update date:2022-09-26
Topics:
Casagrande, Gleison A.
Deflon, Victor M.
Martins, Gabriel R.
Oliveira-Silva, Diogo
Perecim, Givago P.
Pinto, Leandro M. C.
Raminelli, Cristiano
Total syntheses of (S)- and (R)-nuciferine were accomplished through approach involving diastereoselective reaction between a chiral dihydroisoquinoline enamide and 2-(trimethylsilyl)phenyl trifluoromethanesulfonate promoted by CsF, affording a separable mixture of diastereoisomers, which provided (S)- and (R)-nuciferine via simple and efficient transformations.
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