Journal of the Chemical Society. Perkin transactions I p. 3186 - 3195 (1981)
Update date:2022-07-29
Topics:
Jarvest, Richard L.
Lowe, Gordon
Potter, Barry V. L.
A stereospecific method for cyclising D-glucose 6-<16O, 17O, 18O>phosphate and adenosine 5'-<16O, 17O, 18O>-phosphate to their conformationally locked six-membered cyclic phosphate diesters has been developed.Using <16O, 17O, 18O>phosphate esters of known absolute configuration it is shown by 31P n.m.r. spectroscopy, after esterification to the axial and equatorial triesters, that the cyclisation occurs with inversion of configuration.It is now possible, therefore, to determine the chirality at phosphorus of D-glucose 6-<16O, 17O, 18O>phosphate and adenosine 5'-<16O, 17O, 18O>phosphate by this procedure.
View Morewebsite:http://www.amadischem.com
Contact:86-571-89925085
Address:Watts Cosine.No.166.Xiangmao Road.
JIAXING SUNS INTERNATIONAL TRADE CO LTD
Contact:18367306858
Address:No.123,Huixin Avenue,Huimin Dist
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Shandong Topscience Biotech Co., Ltd.
Contact:0633-2619278
Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Doi:10.1016/S0014-827X(03)00165-4
(2003)Doi:10.1016/0008-6215(87)80018-6
(1987)Doi:10.1246/bcsj.76.347
(2003)Doi:10.1016/0040-4039(96)01351-2
(1996)Doi:10.1021/jo00087a014
(1994)Doi:10.1016/S0008-6215(00)80959-3
(1978)
