Tetrahedron Letters p. 1977 - 1980 (1998)
Update date:2022-08-05
Topics:
Arjona, Odon
Borrallo, Cristina
Iradier, Fatima
Medel, Rocio
Plumet, Joaquin
Cyclobexenylsulfones 2 show a different behaviour in their reactions with Na/MeOH system depending on the nature of protecting groups R. In the case of R= TMS, the observed sequence Michael addition-vinylsulfone isomerization-alkynyl to alkenyl reduction has been used for the synthesis of a carbasugar related to the antibiotic Rancinamycin III.
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