Synthesis of 1,1-difluoroalkenes via α,α-difluoro-β-lactones

DOI: 10.1016/S0022-1139(97)00134-6

Source and publish data:

Journal of Fluorine Chemistry p. 41 - 50 (1998)

Update date:2022-08-05

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Authors:

Ocampo, Rogelio

Dolbier, William R.

Paredes, Rodrigo

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Article abstract of DOI:10.1016/S0022-1139(97)00134-6

A new method for the general synthesis of 1,1-difluoroalkenes from ketones is presented.The procedure involves initial condensation of a ketone with the difluoro Reformatsky reagent, hydrolysis to form the α,α-difluoro-β-hydroxy acids, followed by cycliza

Full text of DOI:10.1016/S0022-1139(97)00134-6

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