Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

DOI: 10.1016/S0040-4039(98)00338-4

Source and publish data:

Tetrahedron Letters p. 2783 - 2786 (1998)

Update date:2022-07-31

Topics:

Authors:

Sasaki, Makoto

Inoue, Masayuki

Noguchi, Tetsuji

Takeichi, Atsuo

Tachibana, Kazuo

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Article abstract of DOI:10.1016/S0040-4039(98)00338-4

A new strategy for the construction of O-linked oxepane ring system is described. The present method involves regioselective acetal cleavage by i- Bu₂AlSePh and intramolecular radical cyclization by use of β- alkoxyacrylate.

Full text of DOI:10.1016/S0040-4039(98)00338-4

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