Tetrahedron Letters p. 3025 - 3028 (1998)
Update date:2022-07-31
Topics:
Ovaa, Huib
Leeuwenburgh, Michiel A.
Overkleeft, Herman S.
Van Der Marel, Gijs A.
Van Boom, Jacques H.
The transformation of partially protected aldofuranoses into dienes by Wittig olefination of the anomeric center followed by either allylation or oxopalladation of alkoxy-1,2-propadienes is described. Ring-closing metastasis of the linear dienes gives rise to a variety of highly functionalized and chiral ring-expanded oxepines.
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