Tetrahedron p. 5635 - 5650 (1998)
Update date:2022-07-30
Topics:
Barrero, Alejandro F.
Alvarez-Manzaneda, Enrique J.
Chahboun, Rachid
Two efficient enantiospecific syntheses of wiedendiol-A (1) from (-)- sclareol (7), via 11-bromo-8-drimene (11) and 8-drimen-11-al (3), are reported. The first enantiospecific synthesis of wiedendiol-B (2), via 85.95- driman-11-al (26), by two alternative routes starting from 7 and (+)-cis- abienol (8) is also described. 21 prepared from protocatchhualdehyde (17) was used as somatic synthon for preparing 1 and 2.
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