Rhodium hydride (HRh(CO)(PPh3)3) and rhodium carbonyl (Rh4(CO)8L4) complexes obtained by reaction of Rh(acac)(CO)(L) type complexes with methanol and formaldehyde

DOI: 10.1016/0022-328X(92)83254-F

Source and publish data:

Journal of Organometallic Chemistry p. 239 - 244 (1992)

Update date:2022-08-05

Topics:

Authors:

Trzeciak, A. M.

Ziolkowski, J. J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(92)83254-F

Rhodium(I) complexes of Rh(acac)(CO)(L) type (where L = P(OMe)3, P(OEt)3, P(OPh)3, P(O-o-MeC6H4)3, PPh3, P(p-MeC6H4)3, PMePh2, AsPh3) react with alcohols and formaldehyde.In absence of free ligand (L) only carbonyl complexes of formula Rh4(CO)8(L)4 (or Rh

Full text of DOI:10.1016/0022-328X(92)83254-F

Products guided by the article

Product name:2Rh*4CO*4P(C₆H₅)3={(P(C₆H₅)3)2Rh(CO)2}2

Cas No:20936-09-8

R&D Labs maybe for 20936-09-8

SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Alway Chem, China

website:http://www.alwaychem.com

Contact:+86-532-8586-4000, 8586-5000

Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
HANWAYS CHEMPHARM CO.,LIMITED

website:http://www.hanwayschem.com

Contact:+86-18502787239(whatsapp)-

Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China

Relevant to this article

Tracking Hole Transport in DNA Hairpins Using a Phenylethynylguanine Nucleobase

Doi:10.1021/jacs.7b06998
(2017)
Nickel phenyl complexes with chela ting K²-P,O ligands as catalysts for the oligomerization of ethylene into linear α-olefins

Doi:10.1039/a709204k
(1998)
Efficient general procedure to access a diversity of gold(0) particles and gold(I) phosphine complexes from a simple HAuCl₄ source. Localization of homogeneous/heterogeneous system's interface and field-emission scanning electron microscopy study

Doi:10.1021/ja311258e
(2013)
Fmoc-peptide acid chlorides in fragment coupling: Synthesis of β- casomorphin by 3+2 divergent approach

Doi:10.1080/00397919908085738
(1999)
New Chiral Diphosphine Ligands Designed to Have a Narrow Dihedral Angle in the Biaryl Backbone

Doi:10.1002/1615-4169(20010330)343:3<264::AID-ADSC264>3.0.CO;2-T
(2001)
Synthesis of 1H-diphosphirene, phosphorus-carbon cage and 2,3-dihydro-1,2,3-triphosphete tungsten complexes

Doi:10.1080/10426509708545680
(1997)

Article Doi