Rhodium hydride (HRh(CO)(PPh3)3) and rhodium carbonyl (Rh4(CO)8L4) complexes obtained by reaction of Rh(acac)(CO)(L) type complexes with methanol and formaldehyde

DOI: 10.1016/0022-328X(92)83254-F

Source and publish data:

Journal of Organometallic Chemistry p. 239 - 244 (1992)

Update date:2022-08-05

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Authors:

Trzeciak, A. M.

Ziolkowski, J. J.

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Article abstract of DOI:10.1016/0022-328X(92)83254-F

Rhodium(I) complexes of Rh(acac)(CO)(L) type (where L = P(OMe)3, P(OEt)3, P(OPh)3, P(O-o-MeC6H4)3, PPh3, P(p-MeC6H4)3, PMePh2, AsPh3) react with alcohols and formaldehyde.In absence of free ligand (L) only carbonyl complexes of formula Rh4(CO)8(L)4 (or Rh

Full text of DOI:10.1016/0022-328X(92)83254-F

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