Preparation of 1-alkynyl 2-(trimethylsilyl)ethyl sulfides as thiolate anion precursors for self-assembled monolayers

DOI: 10.1016/S0040-4039(98)00540-1

Source and publish data:

Tetrahedron Letters p. 3701 - 3704 (1998)

Update date:2022-07-30

Topics:

Authors:

Takeda, Hiroyuki

Shimada, Satoru

Ohnishi, Satomi

Nakanishi, Fusae

Matsuda, Hiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00540-1

Syntheses of 1-alkynyl 2-(trimethylsilyl)ethyl sulfides are reported. Deprotection of 2-(trimethylsilyl)ethyl groups using fluoride ions permits the formation of thiolate anions which are trapped by in situ alkylation with methyl iodide and can be used to produce self-assembled monolayers on gold.

Full text of DOI:10.1016/S0040-4039(98)00540-1

Products guided by the article

Product name:Trimethyl-(2-phenylethynylsulfanyl-ethyl)-silane

Cas No:209671-92-1

R&D Labs maybe for 209671-92-1

Airsea(Taizhou) Pharmaceutical Limited(expird)

Contact:+86-576-88057622

Address:Dubei, Duqiao, Linhai, Taizhou, Zhejiang, China Zip: 317016
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.

Relevant to this article

Complete reversal of enantioselection using oxazoline-containing Schiff base ligands derived from l-serine in enantioselective addition of diketene to aldehydes

Doi:10.1016/j.tetasy.2006.09.026
(2006)
Electronic dependence of C-O reductive elimination from palladium (aryl)neopentoxide complexes

Doi:10.1021/ja9806581
(1998)
Doi:10.1021/ja01024a052
(1968)
Generation and Reaction of Samarium(II) Iodide Equivalent from Samarium and Chlorotrimethylsilane/Sodium Iodide System in Acetonitrile

Doi:10.1246/cl.1992.2431
(1992)
The first and convenient synthesis of acyclic dienediynes related to neocarzinostatin chromophore

Doi:10.1016/S0040-4039(98)00693-5
(1998)
Identification of a dihydropyridine as a potent α(1a) adrenoceptor- selective antagonist that inhibits phenylephrine-induced contraction of the human prostate

Doi:10.1021/jm980077m
(1998)

Article Doi