Preparation of 1-alkynyl 2-(trimethylsilyl)ethyl sulfides as thiolate anion precursors for self-assembled monolayers

DOI: 10.1016/S0040-4039(98)00540-1

Source and publish data:

Tetrahedron Letters p. 3701 - 3704 (1998)

Update date:2022-07-30

Topics:

Authors:

Takeda, Hiroyuki

Shimada, Satoru

Ohnishi, Satomi

Nakanishi, Fusae

Matsuda, Hiro

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Article abstract of DOI:10.1016/S0040-4039(98)00540-1

Syntheses of 1-alkynyl 2-(trimethylsilyl)ethyl sulfides are reported. Deprotection of 2-(trimethylsilyl)ethyl groups using fluoride ions permits the formation of thiolate anions which are trapped by in situ alkylation with methyl iodide and can be used to produce self-assembled monolayers on gold.

Full text of DOI:10.1016/S0040-4039(98)00540-1

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