Chemistry Letters p. 2431 - 2434 (1992)
Update date:2022-07-30
Topics:
Akane, Noriyuki
Kanagawa, Yoshinori
Nishiyama, Yutaka
Ishii, Yasutaka
Samarium(II) iodide equivalent was generated from metallic samarium and Me3SiCl/NaI reagent in acetonitrile under ambient conditions.Dehalogenation of α-halocarbonyl compounds and reductive coupling of ketones were successfully carried out by the use of the samarium(II) species, thus generated, in acetonitrile.
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