Generation and Reaction of Samarium(II) Iodide Equivalent from Samarium and Chlorotrimethylsilane/Sodium Iodide System in Acetonitrile

DOI: 10.1246/cl.1992.2431

Source and publish data:

Chemistry Letters p. 2431 - 2434 (1992)

Update date:2022-07-30

Topics:

Authors:

Akane, Noriyuki

Kanagawa, Yoshinori

Nishiyama, Yutaka

Ishii, Yasutaka

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Article abstract of DOI:10.1246/cl.1992.2431

Samarium(II) iodide equivalent was generated from metallic samarium and Me3SiCl/NaI reagent in acetonitrile under ambient conditions.Dehalogenation of α-halocarbonyl compounds and reductive coupling of ketones were successfully carried out by the use of the samarium(II) species, thus generated, in acetonitrile.

Full text of DOI:10.1246/cl.1992.2431

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