Generation and Reaction of Samarium(II) Iodide Equivalent from Samarium and Chlorotrimethylsilane/Sodium Iodide System in Acetonitrile

DOI: 10.1246/cl.1992.2431

Source and publish data:

Chemistry Letters p. 2431 - 2434 (1992)

Update date:2022-07-30

Topics:

Authors:

Akane, Noriyuki

Kanagawa, Yoshinori

Nishiyama, Yutaka

Ishii, Yasutaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.2431

Samarium(II) iodide equivalent was generated from metallic samarium and Me3SiCl/NaI reagent in acetonitrile under ambient conditions.Dehalogenation of α-halocarbonyl compounds and reductive coupling of ketones were successfully carried out by the use of the samarium(II) species, thus generated, in acetonitrile.

Full text of DOI:10.1246/cl.1992.2431

Products guided by the article

Product name:3,6-Dioxa-2,7-disilaoctane, 2,2,4,5,7,7-hexamethyl-4,5-diphenyl-

Cas No:21081-92-5

R&D Labs maybe for 21081-92-5

Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Shanghai Yingrui Biopharma Co., Ltd

Contact:021-3358 8661*8003

Address:shanghai

Relevant to this article

Ansa macrolides as molecular workbenches: Stereocontrolled syn additions to E olefins

Doi:10.1002/(SICI)1521-3773(19980619)37:11<1566::AID-ANIE1566>3.0.CO;2-U
(1998)
Synthesis of internal acetylenes from vinylic tellurides

Doi:10.1016/S0040-4039(98)01085-5
(1998)
Cycloaddition and nucleophilic substitution reactions of the monomeric titanocene sulfido complex (η⁵-C₅Me₅)₂(C₅H₅N)Ti=S

Doi:10.1021/ja980877m
(1998)
(R)- and (S)-3-hydroxy-4,4-dimethyl-1-phenyl-2-pyrrolidinone as chiral auxiliaries in the enantioselective preparation of α-aryloxypropanoic acid herbicides and α-chlorocarboxylic acids

Doi:10.1016/S0957-4166(98)00194-3
(1998)
Novel 5-hydroxytryptamine 4 (5-HT₄) receptor agonists. Synthesis and gastroprokinetic activity of 4-amino-N-[2-(1-aminocycloalkan-1-yl)ethyl]-5- chloro-2-methoxybenzamides

Doi:10.1248/cpb.46.1116
(1998)
Aluminum complexes incorporating bulky nitrogen and sulfur donor ligands

Doi:10.1021/om9802358
(1998)

Article Doi