Synthesis and reactivity of substituted 3- ([(trifluoromethyl)sulfonyl]oxy) 1H-indole-2-carboxylate in palladium- catalyzed reactions

Article abstract of DOI:10.1016/S0040-4020(98)00649-8

Palladium-catalysed Suzuki and Stille reactions of substituted 3- indolyltriflate afforded the corresponding 3-substituted indoles. By contrast, the Heck reaction of allyl alcohol with such triflates gave 2- allyloxy-3-oxoindole derivatives rather than th