Tetrahedron Letters p. 4305 - 4308 (1998)
Update date:2022-08-04
Topics:
Yoshida, Tomoyasu
Chika, Jun-Ichi
Takei, Hisashi
The nucleophilic addition of Grignard reagents and allyltributyltin to chiral ω-tetrahydropyranloxy propanal and butanal derived from L-fucose and D-arabinose gave the alcohols with high diastereoselectivity (up to 51% de by 1,6-asymmetric induction and 95% de by 1.5-asymmetric induction).
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