Oxygen Atom Transfer With Niobocene Ketenes; Baeyer-Villiger Chemistry with Unusual Regioselectivities

DOI: 10.1016/S0040-4039(00)60395-7

Source and publish data:

Tetrahedron Letters p. 7545 - 7548 (1993)

Update date:2022-08-05

Topics:

Authors:

Fermin, Maria C.

Bruno, Joseph W.

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Article abstract of DOI:10.1016/S0040-4039(00)60395-7

Niobocene ketene complex 1 has been utilized as an oxygen atom transfer reagent, converting ketones and aldehydes to esters and carboxylic acids.The steric properties of compound 1 give rise to a series of relative migratory aptitudes that differs from those seen for peracids.The process may be rendered catalytic in 1 with methyltrifluoromethyldioxirane (4). Key Words: Baeyer-Villiger reaction, niobocene complexes, ketenes, oxygen transfer, dioxiranes

Full text of DOI:10.1016/S0040-4039(00)60395-7

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