Tetrahedron Letters p. 4789 - 4792 (1998)
Update date:2022-08-03
Topics:
Clive, Derrick L. J.
Yeh, Vince S. C.
(S)-Pyroglutamic acid was converted into the (phenylthio)acetylene 14, which undergoes radical cyclization to the 7-azabicyclo[2.2.1]heptane 15. Ozonolysis then affords ketone 4, a synthetic precursor of (-)-epibatidine.
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Doi:10.1021/ja980499l
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(1998)Doi:10.1016/S0022-328X(98)00529-4
(1998)Doi:10.1002/anie.201804479
(2018)Doi:10.1016/j.bmcl.2010.02.094
(2010)
