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An octahedral stannylmanganese stannylene complex1,2

DOI: 10.1016/S0022-328X(98)00479-3

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Journal of Organometallic Chemistry p. 125 - 129 (1998)

Update date:2022-08-02

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Authors:

Weidenbruch, ManfredWeidenbruch, Manfred

Stilter, ArturStilter, Artur

Saak, WolfgangSaak, Wolfgang

Peters, KarlPeters, Karl

Von Schnering, Hans GeorgVon Schnering, Hans Georg

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Article abstract of DOI:10.1016/S0022-328X(98)00479-3

Treatment of decacarbonyldimanganese with the alkylarylstannylene RR′Sn (2), R=2,4,6-tBu3C6H2, R′=CH2C(CH3)2-3,5-tBu2C6H3, furnishes the tetracarbonyl-stannylmanganese stannylene complex 3, in which the tin atom of the stannyl group is part of a stannaindan ring system. Reaction of 2 with [(OC)2Fe(NO)2] yields the tetrahedral iron stannylene complex [OC(NO)2Fe=SnRR′] (4). The structures of 3 and 4 were determined by X-ray crystallography.

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Full text of DOI:10.1016/S0022-328X(98)00479-3

Products guided by the article

Product name:Mn(CO)4(((CH3)3C)3C6H2)Sn(CH2C(CH3)2C6H3(C(CH3)3)2)Sn(((CH3)3C)2C6H2C(CH3)2CH2)(CH2C(CH3)2C6H3(C(CH3)3)2)

Cas No:211926-59-9

211926-59-9

R&D Labs maybe for 211926-59-9

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