First metallation of iodo diazines. Iodo and nitrogen directed metallations. Diazines XXII

DOI: 10.1016/S0040-4020(98)00526-2

Source and publish data:

Tetrahedron p. 9701 - 9710 (1998)

Update date:2022-09-26

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Authors:

Ple, Nelly

Turck, Alain

Heynderickx, Arnault

Queguiner, Guy

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Article abstract of DOI:10.1016/S0040-4020(98)00526-2

Lithiation of iodopyrazine and 4-iodo-2-methylthiopyrimidine followed by reaction with various electrophiles was successfully achieved and was used to synthesize new pyrazine and pyrimidine derivatives. Iodo and nitrogen directed metallations were observed.

Full text of DOI:10.1016/S0040-4020(98)00526-2

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