Tetrahedron Letters p. 5999 - 6002 (1998)
Update date:2022-09-26
Topics:
Ohba, Masashi
Nishimura, Yoshikazu
Imasho, Masaaki
Fujii, Tozo
Kubanek, Julia
Andersen, Raymond J.
A chiral synthesis of tri-O-methylimbricatine (2), the tri-O-methyl derivative of the unique benzyltetrahydroisoquinoline alkaloid imbricatine (1) isolated from the starfish Dermasterias imbricata, has been accomplished. As a result of the synthesis, the correctness of the structure and absolute stereochemistry proposed for imbricatine has been unequivocally confirmed.
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(2017)
