Tetrahedron Letters p. 6061 - 6064 (1998)
Update date:2022-08-05
Topics:
Van Hooft, Peter A. V.
Leeuwenburgh, Michiel A.
Overkleeft, Herman S.
Van Der Marel, Gijsbert A.
Van Boeckel, Constant A. A.
Van Boom, Jacques H.
A three-step approach to chiral pyranose [5,4], [5,5], [5,6] and [5,7] unsaturated spiroacetal derivatives from perbenzylated glucopyranolactone 1 is presented. The strategy involves Grignard addition of vinyl or allyl magnesium bromide to 1 to give 2 and
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