Copper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation

DOI: 10.1021/ol403406y

Source and publish data:

Organic Letters p. 524 - 527 (2014)

Update date:2022-09-26

Topics:

Authors:

Chen, Chaohuang

Hou, Chuanqi

Wang, Yuguang

Hor, T. S. Andy

Weng, Zhiqiang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ol403406y

A catalytic trifluoromethylselenolation of aryl and alkyl halides by a Cu(I) catalyst has been developed. A key intermediate, [(phen)Cu(SeCF3)]2 (5) was successfully isolated and characterized by X-ray diffraction. The important role of silver in the tran

Full text of DOI:10.1021/ol403406y

Products guided by the article

Product name:1-methoxy-4-[(trifluoromethyl)selanyl]benzene

Cas No:21506-10-5

R&D Labs maybe for 21506-10-5

Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
SuZhou Hua-Emy Chemical Import and Export Co., LTD.

Contact:+86-512-88804994; +86-512-88804550;

Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
SHANGHAI T&W PHARMACEUTICAL CO., LTD.

website:http://www.trustwe.com

Contact:+86-21-61551413

Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong

Relevant to this article

Copper- A nd DMF-mediated switchable oxidative C-H cyanation and formylation of imidazo[1,2-: A] pyridines using ammonium iodide

Doi:10.1039/d0ob01838d
(2020)
Analogues of a locked nucleic acid with three-carbon 2′,4′- linkages: Synthesis by ring-closing metathesis and influence on nucleic acid duplex stability and structure

Doi:10.1021/jo061225g
(2006)
Stereoselective synthesis of dihydroisocoumarin moiety of microbial agent AI-77-B: A Diels-Alder based strategy

Doi:10.1016/S0040-4039(98)01977-7
(1998)
Synthesis of 6-alkenyl- and 6-alkynylpurines with cytokinin activity

Doi:10.1016/S0040-4020(98)01027-8
(1999)
A new catch-and-release purification method using a 4-azido-3-chlorobenzyl group

Doi:10.1055/s-2001-14623
(2001)
Doi:10.1016/0040-4020(78)80179-3
(1978)

Article Doi