Tetrahedron Letters p. 7309 - 7312 (1998)
Update date:2022-07-29
Topics:
Fujioka, Hiromichi
Nagatomi, Yasushi
Kotoku, Naoyuki
Kitagawa, Hidetoshi
Kita, Yasuyuki
Haloetherification reaction of the chiral ene acetals derived from unsaturated meso-1,2-diols and chiral non-racemic norbornene aldehyde proceeded in an intramolecular manner with an unexpectedly high kinetic control. This method has been successfully employed for the desymmetrization of unsaturated meso-1,2-diols leading to their optically pure derivatives.
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